A remarkably strained cyclopyrenylene trimer that undergoes metal-free direct oxygen insertion into the biaryl C–C σ-bond

A remarkably strained cyclopyrenylene trimer CP3 was synthesized and it underwent the first biaryl C–C σ-bond cleavage by direct oxygen insertion without the aid of any metal agents. A priori highly strained CP3 exhibits the longest wavelength emission among all pyrene-based fluorophores due to the...

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Detalles Bibliográficos
Autores principales: Kurosaki, Ryo, Hayashi, Hironobu, Suzuki, Mitsuharu, Jiang, Julong, Hatanaka, Miho, Aratani, Naoki, Yamada, Hiroko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640197/
https://www.ncbi.nlm.nih.gov/pubmed/31391899
http://dx.doi.org/10.1039/c9sc01777a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640197/
https://www.ncbi.nlm.nih.gov/pubmed/31391899
http://dx.doi.org/10.1039/c9sc01777a

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