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Photo-redox reactivity of titanium-oxo clusters: mechanistic insight into a two-electron intramolecular process, and structural characterisation of mixed-valent Ti(iii)/Ti(iv) products
Small titanium-oxo-alkoxide clusters, [TiO(OR)(O(2)PR′(2))](4), synthesised by the stoichiometric reaction of Ti(O(i)Pr)(4), phosphinic acid and water, undergo a photo-redox transformation under long-wave UV light. The photo-reaction generates blue coloured, mixed-valence Ti(iii)/Ti(iv)-oxo clusters...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640198/ https://www.ncbi.nlm.nih.gov/pubmed/31391912 http://dx.doi.org/10.1039/c9sc01241a |