Contrasting pK(a) Shifts in Cucurbit[7]uril Host–Guest Complexes Governed by an Interplay of Hydrophobic Effects and Electrostatic Interactions

[Image: see text] Cucurbit[7]uril inclusion complexes with guests bearing dimethylamino groups show the expected upward pK(a) shifts, whereas their diethylamino counterparts display a decrease in pK(a) due to the preferential stabilization of the unprotonated form. These results identify the diethyl...

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Detalles Bibliográficos
Autores principales: Basílio, Nuno, Gago, Sandra, Parola, A. Jorge, Pina, Fernando
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640924/
https://www.ncbi.nlm.nih.gov/pubmed/31457209
http://dx.doi.org/10.1021/acsomega.6b00427

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640924/
https://www.ncbi.nlm.nih.gov/pubmed/31457209
http://dx.doi.org/10.1021/acsomega.6b00427

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