Cargando…
Bite-Angle-Regulated Coordination Geometries: Tetrahedral and Trigonal Bipyramidal in Ni(II) with Biphenyl-Appended (2-Pyridyl)alkylamine N,N′-Bidentate Ligands
[Image: see text] Two simple biphenyl-appended (2-pyridyl)alkylamine N-bidentate ligands, L(e) and L(m), having ethylene and methylene spacers between donor groups, with bite angles L(e) ≈ 100° and L(m) ≈ 80°, dictate pseudotetrahedral and trigonal-bipyramidal geometries in six high-spin Ni(II)-hali...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2017
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640959/ https://www.ncbi.nlm.nih.gov/pubmed/31457593 http://dx.doi.org/10.1021/acsomega.7b00119 |