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Bite-Angle-Regulated Coordination Geometries: Tetrahedral and Trigonal Bipyramidal in Ni(II) with Biphenyl-Appended (2-Pyridyl)alkylamine N,N′-Bidentate Ligands

[Image: see text] Two simple biphenyl-appended (2-pyridyl)alkylamine N-bidentate ligands, L(e) and L(m), having ethylene and methylene spacers between donor groups, with bite angles L(e) ≈ 100° and L(m) ≈ 80°, dictate pseudotetrahedral and trigonal-bipyramidal geometries in six high-spin Ni(II)-hali...

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Detalles Bibliográficos
Autores principales:	Sasi, Divya, Ramkumar, Venkatachalam, Murthy, Narasimha N.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640959/ https://www.ncbi.nlm.nih.gov/pubmed/31457593 http://dx.doi.org/10.1021/acsomega.7b00119

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