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Nickel-Catalyzed Transfer Hydrogenation of Benzonitriles with 2-Propanol and 1,4-Butanediol as the Hydrogen Source

[Image: see text] The homogeneous transfer hydrogenation of benzonitrile with 2-propanol or 1,4-butanediol produced N-benzylidene benzylamine (BBA, 85% yield) using 5 mol % [Ni(COD)(2)] as a catalytic precursor and a mixture of Cy(2)P(CH(2))(2)PCy(2) and Cy(2)P(CH(2))(2)P(O)Cy(2) as ancillary ligand...

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Detalles Bibliográficos
Autores principales: Garduño, Jorge A., García, Juventino J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641154/
https://www.ncbi.nlm.nih.gov/pubmed/31457582
http://dx.doi.org/10.1021/acsomega.7b00545