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Nickel-Catalyzed Transfer Hydrogenation of Benzonitriles with 2-Propanol and 1,4-Butanediol as the Hydrogen Source
[Image: see text] The homogeneous transfer hydrogenation of benzonitrile with 2-propanol or 1,4-butanediol produced N-benzylidene benzylamine (BBA, 85% yield) using 5 mol % [Ni(COD)(2)] as a catalytic precursor and a mixture of Cy(2)P(CH(2))(2)PCy(2) and Cy(2)P(CH(2))(2)P(O)Cy(2) as ancillary ligand...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641154/ https://www.ncbi.nlm.nih.gov/pubmed/31457582 http://dx.doi.org/10.1021/acsomega.7b00545 |