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Basic Phosphonium Ionic Liquids as Wittig Reagents

[Image: see text] The possibility of designing a solvent/reagent for Wittig reactions from basic phosphonium salts is explored theoretically. In the suggested R(4)P(+)PhO(–) and Ph(3)PR(+)PhO(–) ionic liquids (ILs), the phenolate anion is prone to remove the α-proton from the alkyl chains, forming a...

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Detalles Bibliográficos
Autores principales: Firaha, Dzmitry S., Gibalova, Anna V., Hollóczki, Oldamur
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641186/
https://www.ncbi.nlm.nih.gov/pubmed/31457625
http://dx.doi.org/10.1021/acsomega.7b00230