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One-Pot Tandem Hiyama Alkynylation/Cyclizations by Palladium(II) Acyclic Diaminocarbene (ADC) Complexes Yielding Biologically Relevant Benzofuran Scaffolds

[Image: see text] A series of palladium acyclic diaminocarbene (ADC) complexes of the type cis-[(R(1)NH)(R(2))methylidene]PdCl(2)(CNR(1)) [R(1) = 2,4,6-(CH(3))(3)C(6)H(2): R(2) = NC(5)H(10) (2); NC(4)H(8) (3); NC(4)H(8)O (4)] were used not only to perform the C(sp(2))–C(sp) Hiyama coupling between a...

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Detalles Bibliográficos
Autores principales: Singh, Chandan, Prakasham, A. P., Gangwar, Manoj Kumar, Butcher, Raymond J., Ghosh, Prasenjit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641338/
https://www.ncbi.nlm.nih.gov/pubmed/31458491
http://dx.doi.org/10.1021/acsomega.7b01974