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Synthesis, Structures, and Reactivity of Single and Double Cyclometalated Complexes Formed by Reactions of [Cp*MCl(2)](2) (M = Ir and Rh) with Dinaphthyl Phosphines
[Image: see text] Reactions of two dinaphthyl phosphines with [Cp*IrCl(2)](2) have been carried out. In the case of di(α-naphthyl)phenylphosphine (1a), a simple P-coordinated neutral adduct 2a is obtained. However, tert-butyldi(α-naphthyl)phenylphosphine (1b) is cyclometalated to form [Cp*IrCl(P^C)]...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641399/ https://www.ncbi.nlm.nih.gov/pubmed/31458676 http://dx.doi.org/10.1021/acsomega.8b00193 |