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Cyclometalated Ir(III) Complex as a Metalloligand and a Selective Cu(II) Sensor: Synthesis and Structural Characterization of a Heterometallic Tetranuclear Ir(III)/Cu(II) Complex

[Image: see text] A cyclometalated Ir(III) complex, [Ir(ppy)(2)(LH)] (2) [LH(2) = 1,2-bis(pyridine-2-carboxamido)benzene; ppyH = 2-phenylpyridine] was synthesized and structurally characterized. [Ir(ppy)(2)(LH)] contains free donor sites and functions as a metalloligand. Accordingly, it interacts wi...

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Detalles Bibliográficos
Autores principales: Chandrasekhar, Vadapalli, Mahanti, Bani, Pandey, Mrituanjay D., Narayanan, R. Suriya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641452/
https://www.ncbi.nlm.nih.gov/pubmed/31458555
http://dx.doi.org/10.1021/acsomega.8b00042