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PPh(3) Propeller Diastereomers: Bonding Motif Ph(PPh(3)) Face-On π-Ar in Half-Sandwich Compounds [(π-Ar)LL′MPPh(3)]

[Image: see text] Chiral-at-metal compounds (R(Ru),S(C))/(S(Ru),S(C))-[CyRu(1O-2N)PPh(3)]PF(6) and (R(Ru),S(C))/(S(Ru),S(C))-[CyRu(2O-1N)PPh(3)]PF(6) were prepared using anions 1O-2N(–) and 2O-1N(–) of the Schiff bases, derived from the hydroxynaphthaldehydes and (S)-1-phenylethylamine. The pure (R(...

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Detalles Bibliográficos
Autores principales: Brunner, Henri, Balázs, Gábor, Tsuno, Takashi, Iwabe, Haruka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641508/
https://www.ncbi.nlm.nih.gov/pubmed/31457942
http://dx.doi.org/10.1021/acsomega.7b01460