Cargando…
PPh(3) Propeller Diastereomers: Bonding Motif Ph(PPh(3)) Face-On π-Ar in Half-Sandwich Compounds [(π-Ar)LL′MPPh(3)]
[Image: see text] Chiral-at-metal compounds (R(Ru),S(C))/(S(Ru),S(C))-[CyRu(1O-2N)PPh(3)]PF(6) and (R(Ru),S(C))/(S(Ru),S(C))-[CyRu(2O-1N)PPh(3)]PF(6) were prepared using anions 1O-2N(–) and 2O-1N(–) of the Schiff bases, derived from the hydroxynaphthaldehydes and (S)-1-phenylethylamine. The pure (R(...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641508/ https://www.ncbi.nlm.nih.gov/pubmed/31457942 http://dx.doi.org/10.1021/acsomega.7b01460 |