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Palladium-Catalyzed Decarboxylative Ortho-Acylation of Tertiary Benzamides with Arylglyoxylic Acids

[Image: see text] A palladium-catalyzed ortho-acylation of tertiary benzamides using arylglyoxylic acids has been described. Unlike the palladium insertion reported to occur in the distorted N–C(O) amide bond of tertiary benzamides, the current study unveils ortho C–H palladation in acylic or cyclic...

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Detalles Bibliográficos
Autores principales: Laha, Joydev K., Patel, Ketul V., Sharma, Sheetal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6641690/
https://www.ncbi.nlm.nih.gov/pubmed/31457692
http://dx.doi.org/10.1021/acsomega.7b00717