Cargando…

New Strategy To Access Enantioenriched Cyclohexadienones: Kinetic Resolution of para-Quinols by Organocatalytic Thiol-Michael Addition Reactions

[Image: see text] Existing stereoselective routes to 2,5-cyclohexadienones involve either desymmetrization of an achiral substrate or have attempted to perform an asymmetric dearomatization of a phenol. Herein, we report proof-of-principle experiments aimed at developing a kinetic resolution as an a...

Descripción completa

Detalles Bibliográficos
Autores principales: Tang, Ting, Moon, Nicholas G., McKay, Lydia, Harned, Andrew. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643461/
https://www.ncbi.nlm.nih.gov/pubmed/31458205
http://dx.doi.org/10.1021/acsomega.8b01787