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Abstraction of the I Atom from CH(3)I by Gas-Phase Au(n)(–) (n = 1–4) via Reductive Activation of the C–I Bond

[Image: see text] Gas-phase reactions of atomic gold anions and small gold cluster anions, Au(n)(–) (n = 1–4), with CH(3)I were investigated to clarify the effect of the cluster size on C–I bond activation and to elucidate the key properties of Au clusters that govern the reactivity. Au(n)I(–) ident...

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Detalles Bibliográficos
Autores principales: Muramatsu, Satoru, Koyasu, Kiichirou, Tsukuda, Tatsuya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643549/
https://www.ncbi.nlm.nih.gov/pubmed/31458312
http://dx.doi.org/10.1021/acsomega.8b02809