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Abstraction of the I Atom from CH(3)I by Gas-Phase Au(n)(–) (n = 1–4) via Reductive Activation of the C–I Bond
[Image: see text] Gas-phase reactions of atomic gold anions and small gold cluster anions, Au(n)(–) (n = 1–4), with CH(3)I were investigated to clarify the effect of the cluster size on C–I bond activation and to elucidate the key properties of Au clusters that govern the reactivity. Au(n)I(–) ident...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643549/ https://www.ncbi.nlm.nih.gov/pubmed/31458312 http://dx.doi.org/10.1021/acsomega.8b02809 |