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Palladium-Catalyzed Synthesis of Amidines via tert-Butyl isocyanide Insertion
[Image: see text] Para-substituted iodobenzenes were reacted with tert-butyl isocyanide and piperidine as nucleophiles in the presence of palladium–diphosphine catalysts. Both single and double insertion of the isocyanide was observed and the corresponding amidines and ketimine–amidines were obtaine...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643982/ https://www.ncbi.nlm.nih.gov/pubmed/31458248 http://dx.doi.org/10.1021/acsomega.8b02010 |