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Regio/Site-Selective Benzoylation of Carbohydrates by Catalytic Amounts of FeCl(3)

[Image: see text] This work uncovered the regio/site-selective benzoylation of 1,2- and 1,3-diols and glycosides containing a cis-vicinal diol using a catalytic amount of FeCl(3) with the assistance of acetylacetone. FeCl(3) may initially form [Fe(acac)(3)] (acac = acetylacetonate) with excess acety...

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Detalles Bibliográficos
Autores principales: Lv, Jian, Luo, Tao, Zhang, Ying, Pei, Zhichao, Dong, Hai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643987/
https://www.ncbi.nlm.nih.gov/pubmed/31458369
http://dx.doi.org/10.1021/acsomega.8b02360