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Room-Temperature, Copper-Free Sonogashira Reactions Facilitated by Air-Stable, Monoligated Precatalyst [DTBNpP] Pd(crotyl)Cl

[Image: see text] A novel application of [DTBNpP] Pd(crotyl)Cl (DTBNpP = di-tert-butylneopentylphosphine) (P2), an air-stable, commercially available palladium precatalyst that allows rapid access to a monoligated state, has been identified for room-temperature, copper-free Sonogashira couplings of...

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Detalles Bibliográficos
Autores principales: Pohida, Katherine, Maloney, David J., Mott, Bryan T., Rai, Ganesha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644404/
https://www.ncbi.nlm.nih.gov/pubmed/31458021
http://dx.doi.org/10.1021/acsomega.8b01868