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Is It Possible To Prepare and Stabilize Triple-Bonded Thallium≡Antimony Molecules Using Substituents?
[Image: see text] The M06-2X/Def2-TZVP, B3PW91/Def2-TZVP, and B3LYP/LANL2DZ+dp levels of theory were used to investigate the effect of substituents on the stability of the triple-bonded RTl≡SbR molecule. For comparison, small groups (F, OH, H, CH(3), and SiH(3)) and sterically bulky substituents, (A...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644622/ https://www.ncbi.nlm.nih.gov/pubmed/31459144 http://dx.doi.org/10.1021/acsomega.8b00643 |