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Cyanide-Free Ce(III)-Catalyzed Highly Efficient Synthesis of α-Iminonitriles from 2-Aminopyridines and Nitroalkenes via Intermolecular Dehydration Reaction

[Image: see text] A direct and rapid method for the synthesis of α-iminonitriles achieved good to excellent yields. A novel intermolecular dehydration reaction between 2-aminopyridines and nitroalkenes is reported via a rare-earth-metal catalyst. The merits of this transformation include cyanide-fre...

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Detalles Bibliográficos
Autores principales: Chen, Zhengwang, Liang, Pei, Zheng, Jing, Zhou, Zhonggao, Wen, Xiaowei, Liu, Tanggao, Ye, Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644690/
https://www.ncbi.nlm.nih.gov/pubmed/31457985
http://dx.doi.org/10.1021/acsomega.8b02214