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Computational Exploration of Counterion Effects in Gold(I)-Catalyzed Cycloisomerization of ortho-(Alkynyl)styrenes
[Image: see text] A detailed theoretical analysis of the mechanism and chemoselectivity for gold(I)-catalyzed reaction of o-(alkynyl)styrene containing an isopropyl and a methyl at the terminal position of the alkene has been reported in this work. Two different counterions (SbF(6)(–) and OTs(–)) we...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644738/ https://www.ncbi.nlm.nih.gov/pubmed/31459067 http://dx.doi.org/10.1021/acsomega.8b01131 |