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Computational Exploration of Counterion Effects in Gold(I)-Catalyzed Cycloisomerization of ortho-(Alkynyl)styrenes

[Image: see text] A detailed theoretical analysis of the mechanism and chemoselectivity for gold(I)-catalyzed reaction of o-(alkynyl)styrene containing an isopropyl and a methyl at the terminal position of the alkene has been reported in this work. Two different counterions (SbF(6)(–) and OTs(–)) we...

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Detalles Bibliográficos
Autores principales: Zhou, Lin, Zhang, Yanwen, Fang, Ran, Yang, Lizi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644738/
https://www.ncbi.nlm.nih.gov/pubmed/31459067
http://dx.doi.org/10.1021/acsomega.8b01131