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Sometimes, the Least Demanding Solution Is the Most Suitable: A Careful Survey of NMR Spectra of a Phosphonium Salt Accounted for Its “Unusual Wittig Reaction”

[Image: see text] Careful product analysis in combination with appropriate supporting experiments unambiguously proves that in contrast to what was previously reported, generation of the phosphonium salt from a β-cyclocitral-derived allylic alcohol and PPh(3)HBr takes place via a proton-driven elimi...

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Detalles Bibliográficos
Autores principales: Fantinati, Anna, Marchetti, Paolo, Trapella, Claudio, Zanirato, Vinicio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644793/
https://www.ncbi.nlm.nih.gov/pubmed/31458946
http://dx.doi.org/10.1021/acsomega.8b01228