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Critical Role of Anions in Platinum(II) Precursors upon the Structural Motifs of Six-Membered Cycloplatinated N,N′,N″-Triarylguanidines
[Image: see text] The reactions of cis-[Pt(OAc)(2)(DMSO)(2)] with 2 equiv of sym N,N′,N″-triarylguanidines, [ArN=C(NHAr)(2)], in toluene under reflux condition for 8 h afforded six-membered cycloplatinated guanidines, [Pt{κ(2)(C,N)}(OAc){κ(1)N(ArN=C(NHAr)(2))}] [sym = symmetrical; Ar = 2-MeC(6)H(4)...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644913/ https://www.ncbi.nlm.nih.gov/pubmed/31458795 http://dx.doi.org/10.1021/acsomega.8b00782 |