Sequential Electrophilic Substitution Reactions of Tungsten-Coordinated Phosphenium Ions and Phosphine Triflates

[Image: see text] Abstraction of chloride from [W(CO)(5){PPhCl(2)}] with AgOSO(2)CF(3) leads to the phosphine triflate complex [W(CO)(5){PPhCl(OSO(2)CF(3))}] which undergoes electrophilic substitution reactions with N,N-diethylaniline, anisole, N,N-dimethyl-p-toluidine, toluene, biphenyl, naphthalen...

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Detalles Bibliográficos
Autores principales: Jayaraman, Arumugam, Nilewar, Shrikant, Jacob, Tyler V., Sterenberg, Brian T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645012/
https://www.ncbi.nlm.nih.gov/pubmed/31457342
http://dx.doi.org/10.1021/acsomega.7b01424

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645012/
https://www.ncbi.nlm.nih.gov/pubmed/31457342
http://dx.doi.org/10.1021/acsomega.7b01424

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