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Sequential Electrophilic Substitution Reactions of Tungsten-Coordinated Phosphenium Ions and Phosphine Triflates
[Image: see text] Abstraction of chloride from [W(CO)(5){PPhCl(2)}] with AgOSO(2)CF(3) leads to the phosphine triflate complex [W(CO)(5){PPhCl(OSO(2)CF(3))}] which undergoes electrophilic substitution reactions with N,N-diethylaniline, anisole, N,N-dimethyl-p-toluidine, toluene, biphenyl, naphthalen...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645012/ https://www.ncbi.nlm.nih.gov/pubmed/31457342 http://dx.doi.org/10.1021/acsomega.7b01424 |