Synthesis of Highly Functionalized 2-Pyranone from Silyl Ketene

[Image: see text] We report a highly functionalized 2-pyranone small molecule prepared from tert-butyl diphenyl silyl ketene using an alkoxide catalyst and thermally induced rearrangement. Treatment of the silyl ketene with a substoichiometric amount of alkoxide led to the formation of a trimer whic...

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Detalles Bibliográficos
Autores principales: Xiang, Yuanhui, Rheingold, Arnold. L., Pentzer, Emily B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645212/
https://www.ncbi.nlm.nih.gov/pubmed/31459075
http://dx.doi.org/10.1021/acsomega.8b01531

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645212/
https://www.ncbi.nlm.nih.gov/pubmed/31459075
http://dx.doi.org/10.1021/acsomega.8b01531

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