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Synthesis of Highly Functionalized 2-Pyranone from Silyl Ketene
[Image: see text] We report a highly functionalized 2-pyranone small molecule prepared from tert-butyl diphenyl silyl ketene using an alkoxide catalyst and thermally induced rearrangement. Treatment of the silyl ketene with a substoichiometric amount of alkoxide led to the formation of a trimer whic...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645212/ https://www.ncbi.nlm.nih.gov/pubmed/31459075 http://dx.doi.org/10.1021/acsomega.8b01531 |