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Stable Platinum(IV) Corroles: Synthesis, Molecular Structure, and Room-Temperature Near-IR Phosphorescence

[Image: see text] A series of stable Pt(IV) corrole complexes with the general formula Pt(IV)[TpXPC](m/p-C(6)H(4)CN)(py), where TpXPC(3–) is the trianion of a tris(p-X-phenyl)corrole and X = CF(3), H, and CH(3), has been synthesized, affording key physicochemical data on a rare and elusive class of...

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Detalles Bibliográficos
Autores principales: Alemayehu, Abraham B., McCormick, Laura J., Gagnon, Kevin J., Borisov, Sergey M., Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645213/
https://www.ncbi.nlm.nih.gov/pubmed/31459069
http://dx.doi.org/10.1021/acsomega.8b01149