Rare and Nonexistent Nitrosyls: Periodic Trends and Relativistic Effects in Ruthenium and Osmium Porphyrin-Based {MNO}(7) Complexes

[Image: see text] Relativistic and nonrelativistic density functional theory calculations were used to investigate rare or nonexistent ruthenium and osmium analogues of nitrosylhemes. Strong ligand field effects and, to a lesser degree, relativistic effects were found to destabilize {RuNO}(7) porphy...

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Detalles Bibliográficos
Autores principales: Demissie, Taye B., Conradie, Jeanet, Vazquez-Lima, Hugo, Ruud, Kenneth, Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645279/
https://www.ncbi.nlm.nih.gov/pubmed/31459176
http://dx.doi.org/10.1021/acsomega.8b01434

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645279/
https://www.ncbi.nlm.nih.gov/pubmed/31459176
http://dx.doi.org/10.1021/acsomega.8b01434

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