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Conformational and Stereodynamic Behavior of Five- to Seven-Membered 1-Aryl-2-iminoazacycloalkanes

[Image: see text] The stereodynamic behavior of 1-arylpyrrolidin-2-imines, having a C(aryl)–N stereogenic axis, has been studied by means of dynamic nuclear magnetic resonance and density functional theory calculations, evaluating the steric effect of ortho-aryl substituents. The rotational barrier...

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Detalles Bibliográficos
Autores principales: Díaz, Jimena E., Mazzanti, Andrea, Orelli, Liliana R., Mancinelli, Michele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648013/
https://www.ncbi.nlm.nih.gov/pubmed/31459658
http://dx.doi.org/10.1021/acsomega.9b00192