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Vinylsilanes in Highly Diastereo- and Regio-Selective Synthesis of Dihydropyrans

[Image: see text] Borontrifluoride etherate (BF(3)·OEt(2)) can be efficiently used for the synthesis of dihydropyrans from triethylsilyl homoallylic alcohols and aldehydes in good yields. The reaction is highly diastereo- and regio-selective.

Detalles Bibliográficos
Autores principales: Borthakur, Upasana, Biswas, Subhamoy, Saikia, Anil K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648048/
https://www.ncbi.nlm.nih.gov/pubmed/31459498
http://dx.doi.org/10.1021/acsomega.8b03635