Vinylsilanes in Highly Diastereo- and Regio-Selective Synthesis of Dihydropyrans

[Image: see text] Borontrifluoride etherate (BF(3)·OEt(2)) can be efficiently used for the synthesis of dihydropyrans from triethylsilyl homoallylic alcohols and aldehydes in good yields. The reaction is highly diastereo- and regio-selective.

Detalles Bibliográficos
Autores principales: Borthakur, Upasana, Biswas, Subhamoy, Saikia, Anil K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648048/
https://www.ncbi.nlm.nih.gov/pubmed/31459498
http://dx.doi.org/10.1021/acsomega.8b03635
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author Borthakur, Upasana
Biswas, Subhamoy
Saikia, Anil K.
author_facet Borthakur, Upasana
Biswas, Subhamoy
Saikia, Anil K.
author_sort Borthakur, Upasana
collection PubMed
description [Image: see text] Borontrifluoride etherate (BF(3)·OEt(2)) can be efficiently used for the synthesis of dihydropyrans from triethylsilyl homoallylic alcohols and aldehydes in good yields. The reaction is highly diastereo- and regio-selective.
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spelling pubmed-66480482019-08-27 Vinylsilanes in Highly Diastereo- and Regio-Selective Synthesis of Dihydropyrans Borthakur, Upasana Biswas, Subhamoy Saikia, Anil K. ACS Omega [Image: see text] Borontrifluoride etherate (BF(3)·OEt(2)) can be efficiently used for the synthesis of dihydropyrans from triethylsilyl homoallylic alcohols and aldehydes in good yields. The reaction is highly diastereo- and regio-selective. American Chemical Society 2019-02-04 /pmc/articles/PMC6648048/ /pubmed/31459498 http://dx.doi.org/10.1021/acsomega.8b03635 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Borthakur, Upasana
Biswas, Subhamoy
Saikia, Anil K.
Vinylsilanes in Highly Diastereo- and Regio-Selective Synthesis of Dihydropyrans
title Vinylsilanes in Highly Diastereo- and Regio-Selective Synthesis of Dihydropyrans
title_full Vinylsilanes in Highly Diastereo- and Regio-Selective Synthesis of Dihydropyrans
title_fullStr Vinylsilanes in Highly Diastereo- and Regio-Selective Synthesis of Dihydropyrans
title_full_unstemmed Vinylsilanes in Highly Diastereo- and Regio-Selective Synthesis of Dihydropyrans
title_short Vinylsilanes in Highly Diastereo- and Regio-Selective Synthesis of Dihydropyrans
title_sort vinylsilanes in highly diastereo- and regio-selective synthesis of dihydropyrans
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648048/
https://www.ncbi.nlm.nih.gov/pubmed/31459498
http://dx.doi.org/10.1021/acsomega.8b03635
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