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Organocatalytic Asymmetric Addition of Aldehyde to Nitroolefin by H-d-Pro-Pro-Glu-NH(2): A Mechanistic Study
[Image: see text] The mechanism of the asymmetric addition of aldehyde (butanal) to nitroolefin (β-nitrostyrene) catalyzed by H-d-Pro-Pro-Glu-NH(2) (dPPE-NH(2); 1) was explored using density functional theory methods in chloroform. By conformational search, it was confirmed that catalyst 1 and its e...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648279/ https://www.ncbi.nlm.nih.gov/pubmed/31459974 http://dx.doi.org/10.1021/acsomega.9b00465 |