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Synthesis of Trimetallic (HPd@M(2)Au(8))(3+) Superatoms (M = Ag, Cu) via Hydride-Mediated Regioselective Doping to (Pd@Au(8))(2+)
[Image: see text] We have recently reported that hydride (H(–)) doped superatom (HPd@Au(8))(+) protected by eight PPh(3) ligands selectively grew into (HPd@Au(10))(3+) by the nucleophilic addition of two Au(I)Cl units. In the present study, (HPd@Au(8))(+) was successfully converted to unprecedented...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648303/ https://www.ncbi.nlm.nih.gov/pubmed/31459817 http://dx.doi.org/10.1021/acsomega.9b00575 |