Synthesis and Reduction of Bimetallic Methyl-Bridged Rare-Earth Metal Complexes, [(C(5)H(4)SiMe(3))(2)Ln(μ-CH(3))](2) (Ln = Y, Tb, Dy)

[Image: see text] The complexes [Cp′(2)Ln(μ-CH(3))](2), (Cp′ = C(5)H(4)SiMe(3); Ln = Y, Tb, Dy) were reduced to determine if these methyl-bridged complexes would form mixed valent 4f(n)5d(1) Ln(II)/4f(n) Ln(III) compounds or bimetallic 4f(n)5d(1) Ln(II) compounds containing 5d(1)–5d(1) metal–metal b...

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Detalles Bibliográficos
Autores principales: Dumas, Megan T., Ziller, Joseph W., Evans, William J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648718/
https://www.ncbi.nlm.nih.gov/pubmed/31459337
http://dx.doi.org/10.1021/acsomega.8b02665

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648718/
https://www.ncbi.nlm.nih.gov/pubmed/31459337
http://dx.doi.org/10.1021/acsomega.8b02665

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