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Regulation of Axial Chirality through Dynamic Covalent Bond Constrained Biaryls

[Image: see text] A strategy of dynamic covalent chemistry within constrained biaryls was developed for the modulation of axial chirality. The ring fusion partners of amide and aldehyde allowed the manipulation of ring/chain equilibrium and chirality transfer within cyclic diastereomeric hemiaminal....

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Detalles Bibliográficos
Autores principales: Zheng, Hao, Ni, Cailing, Chen, Hang, Zha, Daijun, Hai, Yu, Ye, Hebo, You, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648723/
https://www.ncbi.nlm.nih.gov/pubmed/31460119
http://dx.doi.org/10.1021/acsomega.9b01273