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Equilibrium in the Catalytic Condensation of Carboxylic Acids with Methyl Ketones to 1,3-Diketones and the Origin of the Reketonization Effect

[Image: see text] Acetone is the expected ketone product of an acetic acid decarboxylative ketonization reaction with metal oxide catalysts used in the industrial production of ketones and for biofuel upgrade. Decarboxylative cross-ketonization of a mixture of acetic and isobutyric acids yields high...

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Detalles Bibliográficos
Autores principales: Ignatchenko, Alexey V., DiProspero, Thomas J., Patel, Heni, LaPenna, Joseph R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648764/
https://www.ncbi.nlm.nih.gov/pubmed/31460201
http://dx.doi.org/10.1021/acsomega.9b01188