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Synthesis and Reactivity of a Bis-Strained Alkyne Derived from 1,1′-Biphenyl-2,2′,6,6′-tetrol

[Image: see text] The novel “double strained alkyne” 3 has been prepared and evaluated in strain-promoted azide-alkyne cycloaddition reactions with azides. The X-ray crystallographic structure of 3, which was prepared in one step from 1,1′-biphenyl-2,2′,6,6′-tetrol 4, reveals the strained nature of...

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Detalles Bibliográficos
Autores principales: Knighton, Richard C., Sharma, Krishna, Robertson, Naomi S., Spring, David R., Wills, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648819/
https://www.ncbi.nlm.nih.gov/pubmed/31459462
http://dx.doi.org/10.1021/acsomega.8b03634