S(8)-Catalyzed triple cleavage of bromodifluoro compounds for the assembly of N-containing heterocycles

An unprecedented S(8)-catalyzed selective triple-cleavage of bromodifluoroacetamides is disclosed for the first time. Valuable 2-amido substituted benzimidazoles, benzoxazoles and benzothiazoles were obtained in good to excellent yields in a cascade protocol in this strategy. Mechanistic studies sug...

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Detalles Bibliográficos
Autores principales: Deng, Shuilin, Chen, Haohua, Ma, Xingxing, Zhou, Yao, Yang, Kai, Lan, Yu, Song, Qiuling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6657413/
https://www.ncbi.nlm.nih.gov/pubmed/31391905
http://dx.doi.org/10.1039/c9sc01333d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6657413/
https://www.ncbi.nlm.nih.gov/pubmed/31391905
http://dx.doi.org/10.1039/c9sc01333d

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