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Bis[μ-bis­(2,6-diiso­propyl­phen­yl) phosphato-κ(2) O:O′]bis­[(2,2′-bi­pyridine-κ(2) N,N′)lithium] toluene disolvate and its catalytic activity in ring-opening polymerization of ∊-caprolactone and l-dilactide

The solvated centrosymmmtric title compound, [Li(2)(C(24)H(34)O(4)P)(2)(C(10)H(8)N(2))(2)]·2C(7)H(8), was formed in the reaction between {Li[(2,6-(i)Pr(2)C(6)H(3)-O)(2)POO](MeOH)(3)}(MeOH) and 2,2′-bi­pyridine (bipy) in toluene. The structure has monoclinic (P2(1)/n) symmetry at 120 K and the asymme...

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Detalles Bibliográficos
Autores principales: Kalugin, Alexey E., Komarov, Pavel D., Minyaev, Mikhail E., Lyssenko, Konstantin A., Roitershtein, Dmitrii M., Nifant’ev, Ilya E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658944/
https://www.ncbi.nlm.nih.gov/pubmed/31391980
http://dx.doi.org/10.1107/S2056989019006960