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Synthesis, detailed geometric analysis and bond-valence method evaluation of the strength of π-arene bonding of two isotypic cationic prehnitene tin(II) complexes: [{1,2,3,4-(CH(3))(4)C(6)H(2)}(2)Sn(2)Cl(2)][MCl(4)](2) (M = Al and Ga)
From solutions of prehnitene and the ternary halides (SnCl)[MCl(4)] (M = Al, Ga) in chlorobenzene, the new cationic Sn(II)–π-arene complexes catena-poly[[chloridoaluminate(III)]-tri-μ-chlorido-4′:1κ(2) Cl,1:2κ(4) Cl-[(η(6)-1,2,3,4-tetramethylbenzene)tin(II)]-di-μ-chlorido-2:3κ(4) Cl-[(η(6)-1,2...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659333/ https://www.ncbi.nlm.nih.gov/pubmed/31392023 http://dx.doi.org/10.1107/S2056989019008508 |