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Synthesis, detailed geometric analysis and bond-valence method evaluation of the strength of π-arene bonding of two isotypic cationic prehnitene tin(II) complexes: [{1,2,3,4-(CH(3))(4)C(6)H(2)}(2)Sn(2)Cl(2)][MCl(4)](2) (M = Al and Ga)

From solutions of prehnitene and the ternary halides (SnCl)[MCl(4)] (M = Al, Ga) in chloro­benzene, the new cationic Sn(II)–π-arene complexes catena-poly[[chlorido­aluminate(III)]-tri-μ-chlorido-4′:1κ(2) Cl,1:2κ(4) Cl-[(η(6)-1,2,3,4-tetra­meth­yl­benzene)­tin(II)]-di-μ-chlorido-2:3κ(4) Cl-[(η(6)-1,2...

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Detalles Bibliográficos
Autores principales: Merkelbach, Johannes, Frank, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659333/
https://www.ncbi.nlm.nih.gov/pubmed/31392023
http://dx.doi.org/10.1107/S2056989019008508