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Crystal structures of two Cu(II) compounds: catena-poly[[chloridocopper(II)]-μ-N-[ethoxy(pyridin-2-yl)methylidene]-N′-[oxido(pyridin-3-yl)methylidene]hydrazine-κ(4) N,N′,O:N′′] and di-μ-chlorido-1:4κ(2) Cl:Cl-2:3κ(2) Cl:Cl-dichlorido-2κCl,4κCl-bis[μ(3)-ethoxy(pyridin-2-yl)methanolato-1:2:3κ(3) O:N,O:O;1:3:4κ(3) O:O:N,O]bis[μ(2)-ethoxy(pyridin-2-yl)methanolato-1:2κ(3) N,O:O;3:4κ(3) N,O:O]tetracopper(II)
Two Cu(II) complexes [Cu(C(14)H(13)N(4)O(2))Cl](n), I, and [Cu(4)(C(8)H(10)NO(2))(4)Cl(4)](n), II, have been synthesized. In the structure of the mononuclear complex I, each ligand is coordinated to two metal centers. The basal plane around the Cu(II) cation is formed by one chloride anion, one oxyg...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659337/ https://www.ncbi.nlm.nih.gov/pubmed/31392027 http://dx.doi.org/10.1107/S2056989019008922 |