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(1R,2S,4r)-1,2,4-Tri­phenyl­cyclo­pentane-1,2-diol and (1R,2S,4r)-4-(2-meth­oxy­phen­yl)-1,2-di­phenyl­cyclo­pentane-1,2-diol: application as initiators for ring-opening polymerization of ∊-caprolactone

Reductive cyclization of 1,3,5-triphenyl- and 3-(2-meth­oxy­phen­yl)-1,5-di­phenyl­pentane-1,5-diones by zinc in acetic acid medium leads to the formation of 1,2,4-tri­phenyl­cyclo­pentane-1,2-diol [1,2,4-Ph(3)C(5)H(5)-1,2-(OH)(2), C(23)H(22)O(2), (I)] and 4-(2-meth­oxy­phen­yl)-1,2-di­phenyl­cyclo­...

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Detalles Bibliográficos
Autores principales: Komarov, Pavel D., Minyaev, Mikhail E., Churakov, Andrei V., Roitershtein, Dmitrii M., Nifant’ev, Ilya E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659343/
https://www.ncbi.nlm.nih.gov/pubmed/31392020
http://dx.doi.org/10.1107/S2056989019008673