Octa-coordinated alkaline earth metal–dinitrogen complexes M(N(2))(8) (M=Ca, Sr, Ba)

We report the isolation and spectroscopic identification of the eight-coordinated alkaline earth metal–dinitrogen complexes M(N(2))(8) (M=Ca, Sr, Ba) possessing cubic (O(h)) symmetry in a low-temperature neon matrix. The analysis of the electronic structure reveals that the metal-N(2) bonds are main...

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Detalles Bibliográficos
Autores principales: Wang, Qian, Pan, Sudip, Lei, Shujun, Jin, Jiaye, Deng, Guohai, Wang, Guanjun, Zhao, Lili, Zhou, Mingfei, Frenking, Gernot
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6662891/
https://www.ncbi.nlm.nih.gov/pubmed/31358748
http://dx.doi.org/10.1038/s41467-019-11323-5

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6662891/
https://www.ncbi.nlm.nih.gov/pubmed/31358748
http://dx.doi.org/10.1038/s41467-019-11323-5

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