Stereochemical significance of O to N atom interchanges within cationic helicenes: experimental and computational evidence of near racemization to remarkable enantiospecificity

Oxygen atoms of cationic dioxa and azaoxa [6]helicenes can be exchanged by amino groups to form azaoxa and diaza [6]helicenes respectively. The mild reaction conditions developed herein allow the construction of libraries of derivatives with sensitive and/or functionalized side chains. Using enantio...

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Detalles Bibliográficos
Autores principales: Labrador, Geraldine M., Besnard, Céline, Bürgi, Thomas, Poblador-Bahamonde, Amalia I., Bosson, Johann, Lacour, Jérôme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6676467/
https://www.ncbi.nlm.nih.gov/pubmed/31588273
http://dx.doi.org/10.1039/c9sc02127b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6676467/
https://www.ncbi.nlm.nih.gov/pubmed/31588273
http://dx.doi.org/10.1039/c9sc02127b

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