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Thermodynamic and kinetic studies of H(2) and N(2) binding to bimetallic nickel-group 13 complexes and neutron structure of a Ni(η(2)-H(2)) adduct

Understanding H(2) binding and activation is important in the context of designing transition metal catalysts for many processes, including hydrogenation and the interconversion of H(2) with protons and electrons. This work reports the first thermodynamic and kinetic H(2) binding studies for an isos...

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Detalles Bibliográficos
Autores principales: Cammarota, Ryan C., Xie, Jing, Burgess, Samantha A., Vollmer, Matthew V., Vogiatzis, Konstantinos D., Ye, Jingyun, Linehan, John C., Appel, Aaron M., Hoffmann, Christina, Wang, Xiaoping, Young, Victor G., Lu, Connie C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6676469/
https://www.ncbi.nlm.nih.gov/pubmed/31588270
http://dx.doi.org/10.1039/c9sc02018g