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Electronic spectroscopy and nanocalorimetry of hydrated magnesium ions [Mg(H(2)O)(n)](+), n = 20–70: spontaneous formation of a hydrated electron?
Hydrated singly charged magnesium ions [Mg(H(2)O)(n)](+) are thought to consist of an Mg(2+) ion and a hydrated electron for n > 15. This idea is based on mass spectra, which exhibit a transition from [MgOH(H(2)O)(n–1)](+) to [Mg(H(2)O)(n)](+) around n = 15–22, black-body infrared radiative disso...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6677030/ https://www.ncbi.nlm.nih.gov/pubmed/30994636 http://dx.doi.org/10.1039/c8fd00204e |