Strategic Utilization of Multifunctional Carbene for Direct Synthesis of Carboxylic–Phosphinic Mixed Anhydride from CO(2)

Direct synthesis of carboxylic–phosphinic mixed anhydrides has been achieved by treating carbon dioxide with N‐phosphine oxide‐substituted imidazolylidenes (PoxIms) that contain both nucleophilic carbene and electrophilic phosphorus moieties. This novel mixed anhydride was efficiently derivatized in...

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Detalles Bibliográficos
Autores principales: Hoshimoto, Yoichi, Asada, Takahiro, Hazra, Sunit, Kinoshita, Takuya, Sombut, Panukorn, Kumar, Ravindra, Ohashi, Masato, Ogoshi, Sensuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6680262/
https://www.ncbi.nlm.nih.gov/pubmed/27891755
http://dx.doi.org/10.1002/anie.201609710

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6680262/
https://www.ncbi.nlm.nih.gov/pubmed/27891755
http://dx.doi.org/10.1002/anie.201609710

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