Anionic Polymerization of β-Butyrolactone Initiated with Sodium Phenoxides. The Effect of the Initiator Basicity/Nucleophilicity on the ROP Mechanism

It was shown that selected sodium phenoxide derivatives with different basicity and nucleophilicity, such as sodium p-nitrophenoxide, p-chlorophenoxide, 1-napthoxide, phenoxide and p-methoxyphenoxide, are effective initiators in anionic ring-opening polymerization (AROP) of β-butyrolactone in mild c...

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Detalles Bibliográficos
Autores principales: Domiński, Adrian, Konieczny, Tomasz, Zięba, Magdalena, Klim, Magdalena, Kurcok, Piotr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6680796/
https://www.ncbi.nlm.nih.gov/pubmed/31336650
http://dx.doi.org/10.3390/polym11071221

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6680796/
https://www.ncbi.nlm.nih.gov/pubmed/31336650
http://dx.doi.org/10.3390/polym11071221

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